Neutral iodotriazoles as scaffolds for stable halogen-bonded assemblies in solution† †Electronic supplementary information (ESI) available: Details of computational methods, synthesis and characterisation data for all compounds are provided. CCDC 1442418–1442421. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc01974a Click here for additional data file.

pH controlled assembly of a self-complementary halogen-bonded dimer† †Electronic supplementary information (ESI) available: Details of computational methods, synthesis and characterisation data for all compounds are provided. CCDC 1488032–1488035. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc03696a Click here for additional data file. Click here for additional data file.

Synthesis and stabilities of peptide-based [1]rotaxanes: molecular grafting onto lasso peptide scaffolds† †Electronic supplementary information (ESI) available: Experimental procedures and analytical data of all new compounds. CCDC 1520783. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc00021a Click here for additional data file. Click here for additional data file.

Enantioselective Narasaka–Heck cyclizations: synthesis of tetrasubstituted nitrogen-bearing stereocenters† †Electronic supplementary information (ESI) available: Experimental procedures and characterisation data for all compounds are provided. CCDC 1438659 and 1438660. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc04466b Click here for additional data file. Click here for additional data file.

School of Chemistry, University of Bristol, B bris.ac.uk AstraZeneca, Alderley Park, Maccleseld, C AstraZeneca, Pepparedsleden 1, Mölndal, 4 † Electronic supplementary information ( and characterisation data for all compou 1438660. For ESI and crystallographic dat DOI: 10.1039/c6sc04466b ‡ These authors contributed equally. § Author to whom correspondence shou structures of 3b and Pd[(Sa,S)-L-...

Synthesis of malhamensilipin A exploiting iterative epoxidation/chlorination: experimental and computational analysis of epoxide-derived chloronium ions† †Electronic supplementary information (ESI) available. CCDC 1470484 and 1470483. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc03012b Click here for additional data file. Click here for additional data file.

Counterion influence on the N–I–N halogen bond† †Electronic supplementary information (ESI) available: Experimental details of synthesis, compound characterisation, IPE NMR measurements, computational and crystallographic procedures, and crystal data for 1-Ag/I to 7-Ag/I, and 12-Ag. CCDC 1045981–1045995. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01053e Click here for additional data file. Click here for additional data file.

Department of Chemistry and Molecular Bio Gothenburg, Sweden. E-mail: [email protected] University of Jyvaskyla, Department of Chem FI-40014 University of Jyvaskyla, Finland Department of Chemistry and RECETOX, Brno, Czech Republic The Swedish NMR Centre, Medicinaregatan Department of Applied Chemistry, Faculty o Prilaz baruna Filipovića 28a, HR-10000 Zag † Electronic supplementary information synthe...